Install compizconfig-settings-manager. Search for "compiz" in the Unity Dash, or start with ccsm
from the command-line.
sudo apt-get install compizconfig-settings-manager
This windows will open. Type grid
in "Filter" box and from right pane select "Grid" option.
Then this window will open.
Just click on each button (point 1) and then into "Edit <Key name>
" window, choose Grab key combination
and press your alternative key, then click Ok and enjoy
But don't forget, read /!\ Warning /!\ and don't change nothing more!!